![]() ![]() HYGF is privately owned and will never franchise. Erin McKennas Bakery, NYCs legendary vegan & gluten-free bakery, ships nationwide on Goldbelly Shop drool-worthy vegan & gluten-free cakes. Everything we sell is dairy-free, nut-free and gluten-free. Love is put in to all our cakes and desserts from the inside out, so not. This list features the best vegan-friendly bakeries in Amsterdam, as determined by the highest scores calculated from Happ圜ow community member reviews. Bunners Bakeshop is Torontos premier vegan and gluten-free bakery. We offer a delicious range of cake and dessert flavours and we have an extensive range of gluten and dairy free options. Do you have other locations? Can we franchise? Can we wholesale your stuff?ĭecatur will open September 2023 □, Adair Park will open late 2023 or early 2024. Mad About Cakes is a boutique bakery based in Melbourne Australia, specialising in dietary requirement desserts and unique custom cake creations. That is our main project to tackle when our commissary kitchen opens late 2023-early 2024. ![]() Yeah, text us! It just depends on what we have going on that day/week, nothing is guaranteed OR off limits except custom cakes. If you come in 30 minutes before we close, you might leave disappointed, which we definitely don’t want! □ And although we wish we were fortune tellers (so cool right?) we are not □☹️, and cannot anticipate when certain items will sell out. Whether you’re celebrating your little one’s first birthday or your grandmother’s 100th, we’ve got the perfect cake for every celebration. When we first open our doors, our inventory is its most diverse and plenty. ![]() If your heart is set on trying a specific product, we always suggest coming at our open time. Help us do that by coming early and getting an amazing haul! □ When should I come if I want _? How quickly do you sell out of _? Simply, we want to avoid waste–wasting product and wasting money. ![]()
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![]() ![]() Note: Remember that these aren't the overall enthalpy changes for the reactions when the metal reacts with water. ![]() If we put values for all these steps into a table, they look like this (all values in kJ / mol): If you aren't happy about enthalpy changes, you might want to explore the energetics section of Chemguide, or my chemistry calculations book. If you don't know about Hess's Law, you probably aren't likely to be making much sense of all this bit of the page anyway. All we are doing is inventing an imaginary route from the start to the end point of the reaction, and using Hess's Law to say that the overall enthalpy change will be exactly the same as we can calculate using this imaginary route. Note: There is no suggestion that the reaction actually happens by this route. Then ionise the metal by supplying its first ionisation energy.Īnd finally, you would get hydration enthalpy released when the gaseous ion comes into contact with water. You can calculate the overall enthalpy change for this process by using Hess's Law and breaking it up into several steps that we know the enthalpy changes for.įirst, you would need to supply atomisation energy to give gaseous atoms of the metal. Overall, what happens to the metal is this: In each case, you start with metal atoms in a solid and end up with metal ions in solution. When these reactions happen, the differences between them lie entirely in what is happening to the metal atoms present. The values for rubidium and caesium are calculated indirectly from the Li, Na and K values and other information which you will find in a later table on this page. The lithium value agrees almost exactly with a value I found during a web search. For lithium, sodium and potassium, they are calculated values based on information in the Nuffield Advanced Science Book of Data (page 114 of my 1984 edition). ![]() Note: Apart from the lithium value, I haven't been able to confirm these figures. They are all fairly similar and, surprisingly, lithium is the metal which releases the most heat during the reaction! You will see that there is no pattern at all in these values. Note: That's the same equation as before, but I have divided it by two to show the enthalpy change per mole of metal reacting. ![]() The table gives estimates of the enthalpy change for each of the elements undergoing the reaction: You might think that because the reactions get more dramatic as you go down the Group, the amount of heat given off increases as you go from lithium to caesium. Looking at the enthalpy changes for the reactions The Group 1 metals become more reactive towards water as you go down the Group. Caesium hydroxide and hydrogen are formed Rubidium hydroxide solution and hydrogen are formed.Ĭaesium explodes on contact with water, quite possibly shattering the container. It reacts violently and immediately, with everything spitting out of the container again. Rubidium is denser than water and so sinks. This time the normal hydrogen flame is contaminated by potassium compounds and so is coloured lilac (a faintly bluish pink). Potassium behaves rather like sodium except that the reaction is faster and enough heat is given off to set light to the hydrogen. The colour is due to contamination of the normally blue hydrogen flame with sodium compounds. If the sodium becomes trapped on the side of the container, the hydrogen may catch fire to burn with an orange flame. The sodium moves because it is pushed around by the hydrogen which is given off during the reaction. A white trail of sodium hydroxide is seen in the water under the sodium, but this soon dissolves to give a colourless solution of sodium hydroxide. Sodium also floats on the surface, but enough heat is given off to melt the sodium (sodium has a lower melting point than lithium and the reaction produces heat faster) and it melts almost at once to form a small silvery ball that dashes around the surface. The reaction generates heat too slowly and lithium's melting point is too high for it to melt (see sodium below). It gradually reacts and disappears, forming a colourless solution of lithium hydroxide. Lithium's density is only about half that of water so it floats on the surface, gently fizzing and giving off hydrogen. In each of the following descriptions, I am assuming a very small bit of the metal is dropped into water in a fairly large container. This equation applies to any of these metals and water - just replace the X by the symbol you want. In each case, a solution of the metal hydroxide is produced together with hydrogen gas. It uses these reactions to explore the trend in reactivity in Group 1.Īll of these metals react vigorously or even explosively with cold water. This page looks at the reactions of the Group 1 elements - lithium, sodium, potassium, rubidium and caesium - with water. REACTIONS OF THE GROUP 1 ELEMENTS WITH WATER Reactions of the Group 1 elements with water ![]() ![]() ![]() It will also indicate which programs you might want to remove to free up some disk space. You also get a startup optimizer which analyzes all the programs that launch when you start up your device and shows you the time it takes for each to load and allows you to disable any of the programs or delay the launch of any of the programs. Once complete you get a detailed report showing all the files and any changes it also allows you to exempt a category such as chrome cookies. Privacy Cleanup – Shows browser cache, cookies and Internet history on any internet browser you currently use.Registry Cleanup – shows erroneous files such as help files and Shared DLLs.Disk Cleanup – Shows Junk, Temporary and cache files.This provides a scan on your system and puts your system files into the following categories: These utilities include a tune-up tool called OneClick Optimizer. The main difference is the utilities page no longer tries to upgrade, it actually offers you some useful utilities. Bitdefender Total Security when installed on a windows device is very similar to its Internet security option. ![]() If you are a user who has experience of Bitdefender other software packages. Bitdefender is currently offering special offer security for 5 devices for $39.98 for 1 year or $119.99 for the 3-year package available from Bitdefender Using Bitdefender on a Windows Laptop When using Bitdefender on your laptop it also offers an anti-theft option which we will discuss later in this review. So Bitdefender total security offers support for all your devices. Alternately, you can opt for a free antivirus, which offers the same basic virus protection, without the extra features. What is Bitdefender Total Security in a nutshell offers all the entry-level security options you come to expect but also offers some advanced features such as online backup, system performance optimization and offers support for PC, macOS and both IOS & Android. Since most of us are now working from home due to the current pandemic we need to make sure more then ever we are safe online and this is where cybersecurity company Bitdefender offer its Total Security option to keep them confidential work files safe and make sure you are protected against any cyberattack that could cause you and the company you work for no end of problems. ![]() ![]() ![]() Residents should check-in at the halls designated rally point which is identified in the first-floor meeting. All persons are to move away from the entrances and not block the street or parking lots. As residents exit the building, they are to proceed to the designated evacuation area.Before opening any door, check for heat using the back of your hand if it’s hot do not open that door seek another escape route.If a fire or smoke is detected, locate the nearest pull box and activate it. ![]()
![]() Calihan says many of Moss’ fans were people who wouldn’t normally consider themselves VR gamers, in part because it’s so approachable.We are a common ground for discussion relating to Virtual Reality and Virtual Worlds.ĭiscussion relating to any and all facets of virtual reality is encouraged. Moss’ seated gameplay, lack of complex controls, and what Calihan calls its “universally appealing” fantasy aesthetic are also attempts at removing the blocks that keep many players away from VR. Players won’t linger in the game’s environments longer just to enjoy the scenery they can also expect new and more challenging puzzles, but hopefully without some of the friction that made repeated attempts to clear rooms frustrating in the first game. That doesn’t mean Moss: Book II is removing challenge altogether. “Players will be surprised at how strongly they feel.” Players can expect to spend more time in individual rooms, where leaning and moving to get a better look at their diorama structures is another source of joy. You’re going to help through those things and she’s going to depend on you.”įocusing on joy led the team to refine Moss: Book II’s puzzles, removing roadblocks and elements that players found frustrating in the first game. Any time you’re on an epic journey you expect ups and downs. Polyarcīut as Calihan tells Inverse, “It’s not all happy. ![]() Moss: Book II adds new enemies and puzzles types to the mix. ![]() ![]() The relationship between Quill and the Reader, interactions with the environment, the game’s epic story - these are all meant to bring joy to players. Throughout our conversation, one word kept coming up in Calihan’s responses: joy. “Players will be surprised at how strongly they feel about the events unfolding before them,” Calihan says. The sequel will be “a more cinematic experience,” with Quill interacting with other characters in the game world as the Reader looks on, as opposed to the original, where voiceover and storybook interludes did most of the narrative heavy lifting. It’s roughly 50 percent longer than Moss, addressing a common complaint from players that the original’s four-hour runtime was too short. Polyarc also wants the story in Moss: Book II to strengthen the bond between Quill and the Reader. “The biggest thing we want players to come away with is the emotional connection.” A massive hammer, for example, is too heavy for Quill to heft completely on her own, so the Reader has to lift it into the air, allowing Quill to deliver a powerful knockout blow. New weapons and combat skills also bring Quill and the Reader closer. This time around, players can create bridges and climbable surfaces made from vines, giving Quill new ways to move through the environment. On a larger scale, it comes from new options in exploration and combat. On a small scale, that means better interactions with the environment, like grass moving realistically when Quill or the Reader’s hand brushes against it. Moss: Book II aims to accomplish that in big and small ways throughout the game. Only Quill can see the player in their role as the Reader. “The biggest thing we want players to come away with is the emotional connection with Quill being stronger than ever,” Calihan says. It’s no surprise, then, that Polyarc is zeroing in on the player’s relationship with Quill for the sequel. That unique positioning, which makes the player a guide rather than the game’s protagonist, is a big part of what made the puzzle platformer Moss stand out in a VR field dominated by bombastic experiences like jetpack basketball and hypnotic rhythm games. She reaches out to the Reader, reacts to the world around her, and notices objects in the environment without the player’s help, all of which makes Quill feel more real than most video game characters. But while you control Quill’s movement, she always feels like a separate character, someone you communicate with rather than embody. As the Reader, you can reach into the world to move objects and open doors for Quill, who you then control through platforming and combat challenges. In both Moss and its sequel, the player takes on the role of the Reader, an invisible spirit only Quill can see with the help of a magical artifact. “The reason we’re making Moss is we want to create an experience that only VR can allow, which is putting you in the middle of the story with Quill,” Calihan tells Inverse. Based on a recent gameplay demo and a conversation with Polyarc’s Principal Artist Coolie Calihan, Moss: Book II is doubling down on what made the original one of VR’s most memorable narrative experiences. ![]() It did so not with flashy, mind-blowing effects or an acrobatic control scheme, but with immersive level design, a captivating story, and one adorable mouse named Quill. Moss: Book II’s Spring 2022 release date is fast approaching. ![]() ![]() ![]() CodeMaidĬodeMaid is an open-source extension for Visual Studio that simplifies the process of cleaning and organizing your code. As a free extension integrated with Visual Studio, it’s an essential tool for any developer looking to improve their productivity and code quality. With its intelligent suggestions, context-aware code completion, and custom model training capabilities, IntelliCode helps developers write better code, faster. In conclusion, Visual Studio IntelliCode is a powerful extension that leverages artificial intelligence to enhance your coding experience. ![]() Use multiple programming languages supported by IntelliCode.Work on projects with unique coding patterns that can benefit from custom model training.Need context-aware code completion for improved accuracy.Want to boost their coding efficiency with AI-powered suggestions.Visual Studio IntelliCode is particularly beneficial for developers who: May not cover all coding patterns or libraries.Requires an internet connection for certain features, such as custom model training.Integrated with Visual Studio and free to use.Support for multiple programming languages.Custom model training for tailored suggestions based on your project.Context-aware suggestions that improve code quality.AI-powered code completion for increased efficiency.IntelliCode offers various features, such as AI-powered code completion, context-aware suggestions, custom model training based on your codebase, and support for multiple programming languages like C#, Python, JavaScript, TypeScript, and more. Developed by Microsoft, IntelliCode provides intelligent suggestions and code completion, helping developers write code more efficiently and with fewer errors. Visual Studio IntelliCode is an innovative extension that uses artificial intelligence to enhance your coding experience. While it may come with a performance cost in some cases, the benefits offered by ReSharper’s powerful features make it a valuable addition to any developer’s toolkit. In summary, ReSharper is an excellent extension for developers looking to improve their code quality, streamline their development process, and maintain a consistent coding style across their team. Want to enforce coding standards and best practices across their team.Need to navigate and search through codebases efficiently. ![]() Require advanced code analysis and refactoring tools.ReSharper is particularly useful for developers who: Requires a paid license for long-term use, although a free trial is available.Can have a performance impact on Visual Studio, particularly in large projects.Regular updates and support from JetBrains.Seamless integration with other JetBrains tools.Intelligent code completion and suggestions.Comprehensive set of tools for improving code quality.It also integrates seamlessly with other JetBrains tools like dotTrace and dotMemory. ReSharper offers numerous features, such as code analysis, refactoring tools, navigation and search capabilities, code templates, and support for various programming languages like C#, VB.NET, ASP.NET, and more. ![]() ![]() Keeping your arms straight, bend your shoulders backwards to take the dumbbell down behind your head without raising your torso or feet off the original position.With both hands forming a diamond shape together, hold the dumbbell straight up above your chest.Your torso should be in line with the thighs and the chest. Your knees should be bent at 90 degrees and feet anchored on the floor.Lie across a bench with your shoulder blades resting on it, and your head suspended slightly above the edge of the bench.A medium to heavy dumbbell, according to your strength level.Alternative exercises for dumbbell pulloverīefore beginning any workout, you should always warm-up and do some mobility exercises to enable the full range of motion on the targeted muscle groups.How to do the dumbbell pullover correctly.Read more: Best workout for a bigger chest Read on to know why you should include this simple exercise in your weekly routine and how to do it correctly: Former actor and governor of California, US, Arnold Schwarzenegger made it popular at his peak and fellow competitors all respected the exercise’s benefits towards building a bigger chest, but it remains restricted to the regime of the more serious fitness enthusiast even today. While the dumbbell pullover isn’t given the same importance as some other exercises, it has been a favourite among professional bodybuilders and fitness trainers. However, there is no harm in performing the exercise with the slightly different techniques on different days of the week. The truth is that following the standard technique is actually good enough to exercise both muscle groups. The result: dumbbell pullovers are often shuttled and shared between back workout day and chest workout day! Some people find a solution to this problem by tweaking their technique slightly, to target either the back muscles or the chest muscles (depending on the area they are focusing on that day). This is because the dumbbell pullover works both the pectoral muscles in the chest as well as the latissimus dorsi muscles in the back. Now, there is a debate around whether the dumbbell pullover exercise should be performed on the day when you’re working out your chest or when you're doing back exercises. This is where the dumbbell pullover comes in. However, it is important to train the muscles from different angles and movements for a complete workout. ![]() Perform one repetition of the dumbbell pullover and finish with the arms straight as you hold in a tabletop position.The bench press - whether it is a flat bench press workout, an incline bench press workout or decline bench press - is one of the pet exercises to work the chest muscles. You'll be in a dead bug position with straight legs. Then, keeping the knees bent, lift the feet off the floor so that the knees are positioned over the hips. In this version, you'll start out in the basic position. ![]() You can combine a dumbbell overhead press with a lower leg extension to create a new type of exercise. If there's any movement at all in the hips, this becomes a total body exercise with the lower body supporting and stabilizing and the upper body moving. Keeping the head and neck supported on the ball, engage the abdominal and gluteal muscles to keep the hips stable and elevated. In lieu of a bulky weight bench, use an exercise ball instead. ![]() Hoisting your legs a few inches above the bench will give your core a bit of a workout, too. This simple change will increase the load on your chest and back muscles, making each movement more challenging. To increase the difficulty of the dumbbell pullover, choose a heavier weight. ![]() ![]() ![]() Blizzard has not publicly commented on the change yet. While I think most people understood that Hearthstone cards weren’t canon or meant to be taken seriously as such, this is just another step in that direction to differentiate it. Remember how upset some people were because of the Ragnaros Lightlord card? By dropping the Heroes of Warcraft moniker they can move the game toward making it’s own little Warcraft-like universe without stepping on the toes of the Warcraft team. Not only does this make sense from a marketing standpoint to just refer to the game as Hearthstone, but the design team since League of Explorers has done a very good job at making their own lore and stories within the Warcraft universe that aren’t necessarily canon. ![]() We have 2 free hearthstone logo png, vector logos, logo templates and icons. Not so fast on that front, I think the change is relatively simple to explain. Search results for hearthstone logo png icon vector. Several people are wondering, what does this mean? Is it possible we might be seeing other Blizzard franchises finding it’s way into Hearthstone? The subreddit made the change about 4 days ago, so it appears this has been something Blizzard has been changing in the last week. So this is a very intentional decision by Blizzard to start referring to the game as just Hearthstone instead of Hearthstone: Heroes of Warcraft. ![]() Hearthstone subreddit moderator /u/deviouskat89 even explained that Blizzard sent them the new logo asking if it could be changed on the subreddit. Festival of Legends has been out for two weeks and the meta has already undergone plenty of. Sure enough, if you go to the official pages you will see the new logo below: Hearthstone Standard Meta Snapshot: Let the Festivities Begin. The subtitle of “Heroes of Warcraft” was being removed. An alert redditor /u/VdeVenancio noticed that the Hearthstone official logo was being changed on the official website, on the app, and was even changed on the Hearthstone subreddit. ![]() ![]() ![]() Once the download completes, the installation will start and you'll get a notification after the installation is finished. BombSquad Remote will be downloaded onto your device, displaying a progress.A pop-up window with the permissions required by BombSquad Remote will be shown.Tap on the Install button located below the search bar and to the right of the app icon. ![]()
![]() ![]() On my main account which Im in chapter 18, I have only gotten Bipson through divination and I've pulled a LOT more on that account. On one of secondary accounts that I made I pulled both Bipson and Juri from regular x10 pulls before I even hit chapter 6. When you go to a casino and drop $100 and lose it all, are the machines rigged? What about if I win the jackpot, is that rigged as well? The truth is their belief holds as much truth and facts that it's rigged as saying god is/isnt real. The thing with anything that is based on chance is many believe something is rigged because it's what they believe. Ive done about 8 x10 pulls trying to get a solid ranked Bispon and managed to get enough to get him up to S+ so far. Thought someone could have missed either of these: SFDLAUNCH - 300 gems ANIMEAWARDS2023 - 500 gems comments sorted by Best Top New Controversial Q&A Add a Comment Brad-Blunt. The thing is this is all evidence but not proof. View community ranking In the Top 5 of largest communities on Reddit. I did a single pull and got Bipson on my first try. I've seen multiple GM Ken's get pulled on the 13th Tear and many received Bipson on their first Divination pull, myself included. which is just pointless because all it does it bring you to another wall with a higher level number on it.The truth is nobody knows for sure. Which I actually sort of enjoyed for a few weeks, at which point you hit a hard wall to your progress and have to choose between a month of farming resources or spending real money in order to level up. There's no actual SF gameplay to it, it's just team management and a bit of puzzle solving. Most of the store options are just giving you next to nothing for your money. but you get about 1500-2000 gems per day just from logging in and doing the daily quests. Diablo had an insanely high ceiling that would take a lifetime to max out a character (or half a million dollars). An astonishing conspiracy is about to be revealed Join Ryu and Ken on their journey to the Fighting Tournament, and take this adventure. Street Fighter: Duel is the official Street Fighter RPG mobile game for the casual Street Fighter fan, where you can collect and upgrade a team of recognizable fighters and battle your way through an original story or against friends and powerful opponents around the world. It's a totally different kind of shittiness from Diablo Immortal. By: Shaun Savage - Posted: July 30, 2023, 12:58pm MST Image: Capcom Street Fighter Duel aka SF Duel is a mobile game created by A PLUS JAPAN/Crunchyroll Games that is available for multiple platforms. Here, you can discover who’s more likely to lay the smackdown, and what combatants might run home to mommy. So we just had to put together this Street Fighter: Duel tier list. you are making significant progress in the game. Kayleigh Partleton Published: 2 weeks ago Street Fighter: Duel There are a lot of characters in the Street Fighter franchise, many of which are present in the mobile game. At least in other games if you buy a bunch of gems etc. Want to discuss Capcom in general? Check out r/capcom./r/fighters - A catchall subreddit for when one game isn't enoughĪ Newbie friendly fighting game community.Ī SF6 hangout for character specific combos & tech./r/sf6avatars - Where you can go for the most heinous or beautiful of creations./r/modfighters - a repository for street fighter modifications.TopTier - Find a fighting game event near you.Two minute tutorials - Absolute beginner help.Got results from your local tournament? Report them hereĪnd compare with players from around the world! Resources Welcome to r/StreetFighter, a subreddit dedicated to build the fighting game community, harbor a healthy competitive nature, and be welcoming to players and fans alike. ![]() |
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